A biodegradable cellulose fibrous membrane comprising cellulose microfibers and nanofibrils with enhanced interaction through crosslinking structure
نویسندگان
چکیده
Abstract The petroleum‐based materials are widely used in daily life, which inherently tough to degrade, increasingly polluting the environment and affecting human health. Cellulose fibrous membrane, ubiquitous, low‐cost, biodegradable material, can serve as a promising substitute. Herein, cellulose membranes were constructed with microfibers made from wood particle fibers (WPF) mechanical properties enhanced by introducing crosslinking system. membrane of original WPF showed low tensile strength (0.1 KPa) elastic modulus (1 MPa). By adding 10 wt% nanofibrils (CNFs), prepared exhibited an increase (0.525 MPa) (535 MPa), respectively. To further improve properties, sodium alginate (SA) Ca 2+ introduced crosslink CNFs promote interaction among SA, microfibers, resulted substantial (5.62 (1660 due formation interpenetrating entanglements anchors. normalized fracture energy crosslinked hybrid was 100.38 times higher than that 16 un‐crosslinked comprising CNFs. This strategy foundation for preparing mechanically via crosslinking, making it possible replace plastics.
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ژورنال
عنوان ژورنال: Polymers for Advanced Technologies
سال: 2023
ISSN: ['1042-7147', '1099-1581']
DOI: https://doi.org/10.1002/pat.6121